Psychological anime? Uh, not sure what you've seen, other than I checked that you haven't seen Boogiepop Phantom, so I'll suggest that. For a few more that are all different, I suppose Id: Invaded, Psycho-Pass, Lain, first season of Higurashi, and certain Satoshi Kon films and Paranoia Agent. Kara no Kyoukai is also a popular one.
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