Sister Miyako

Kannazuki no Miko
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Kannazuki no Miko
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Sister Miyako (ミヤコ)

The Second Neck (二の首, Ni no kubi), she is a purple-haired nun who is the first Orochi to appear and attack, having lost her faith due to living through a terrible war (presumed somewhere in South America due to her tanned skin color which is a common stereotype in manga and anime). Although there is little co-operation among the Orochi, she seems to be the closest thing therein to a second-in-command and the most cool-headed of the lot; she can control Girochi and induce some semblance of cooperation among the three other female Necks.

(Source: Wikipedia)

Voice Actors
Ootani, Ikue
Fahn, Melissa
Márquez, Rosalinda