 If you liked
Shinseiki Evangelion
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 ...then you might like
Sidonia no Kishi
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They both deal with mysterious beings trying to destroy humanity, focus more on character development than mech battles, and are somewhat dark in nature.
Sidonia is basically EVA in space. Alien lifeforms are attacking humanity for unknown reasons and it's up to an unlikely rookie pilot to help stop them. Great and realistic action scenes mixed with a solid story and an awesome sci-fi setting.
Mysterious, powerful aliens seek to destroy humanity, who has taken shelter in a defensive base. The only way to fight these intruders is by employing humanoid gundam-like robots, requiring capable humans to pilot them. Both focus on the portrayal of human psychological conditions.
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Recommended by bunny1ov3r
Both animes have people getting into massive robots and fighting off aliens that come from outer space. Both set in the future.
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Recommended by meowneko999