Hibari x I-pin

Episode 15 (Anime)/Chapter 38 (Manga) Episode 15/Chapter 38 is where it all begins, in the last page where Vongola and Cavallone family playing the snowball fights Tsuna then goes and tries to capture Leon but is surprised to see that Kyoya Hibari captured it himself. He feints an attack on Tsuna before leaving to do some of his prefect duties. However before he leaves, I-Pin sees him and activates her Pinzu-Timed Super Explosion causing Reborn to win the snowball fight. This is their first meeting, surprisingly Ipin likes Hibari's face to the point she becomes embrassed and activated her pinzu explosions. Accurate terms of "love at first sight..." Episode 17 Hibari is seen in hospital and currently sleeping, Ipin as usual activating her Pinzu explosion because she sees him sleeping cutely~ Ipin obviously can't resist Hibari's handsome face LOL Episode 18 After what happens to previous episodes, this is the valentine episode where everyone gives chocolate to people they like. In the last part of this episode, Ipin is seen to give her chocolate to Hibari and Hibari smiles genuinely! **FUNFACT that 18 is Hibari's number in the series/Hibari's trademark and coincidentally, episode 18 is the episode where he first smile genuinely due to Ipin's chocolate!~ Even a violent, fighting maniac guy can't help but smile because this might be the first chocolate he ever gets LOL Episode 33 (Anime)/Chapter 58 (Manga) This is the chapter of summer festival where the money that Tsuna and co. get from selling choco banana is getting stolen by thug. Tsuna, Ipin and Lambo are trying to take it back and they coincidentally meet Hibari here. As usual Ipin getting embrassed and activating her Pinzu explosions causing her (with Lambo) to go explode. This is the first time where Hibari fighting alongside his family (Tsuna, Gokudera, Yamamoto) when he is trying to take money from Tsuna, he is stopping his actions because he sees Ipin looks worried. Even a violent, fighting maniac guy can't help but be gentle to the woman who gives him chocolate~ awww Episode 70, Episode 73 Just the usual Hibapin gag where Ipin meets Hibari and she goes dokaan for him~ <3 Episode 130+ There's not many of their moments in the future arc due to seriousness of this arc, but in this episode Kusakabe surprisingly bringing Ipin along by future Hibari's order. It's just weird considering Ipin isn't a Vongola Guardian unlike Chrome and Lambo, why is Hibari ordering to bring Ipin too? Kusakabe, Ipin, Lambo and other vongola guardians who already passed out unable to fight are all protected by Young Hibari who is already the last line of defense. They are together till the end, captured by Irie and saved by Tsuna. Episode 147 (Anime Filler Only, Arcobaleno Arc) While this arc is anime filler only, this is an interesting episode where Fon and Hibari meets, Ipin is trying to help Tsuna catching Fon for passing Arcobaleno trials (and thanks to her, Fon is able to be caught), in this episode Fon is telling everyone that he always receives letter from Ipin about Vongola and her crush (Hibari). Surprisingly in this episode Ipin doesn't activate her Pinzu explosions when she sees her master but she's instantly activating her Pinzu explosions when she sees Hibari. Might confirm that her love for her master and her love for hibari is something different. even with Ipin's master (Fon) being there, she still activates her Pinzu Explosions in front of Hibari, clearly is not just "face that looks similar"

PlayStation 2 game Katekyo Hitman Reborn! Let's Assassinated? Hit Guide for the Tenth Event Targeted, the player can pretend to be I-Pin to, among other things, talk to Kyoya to gain points. In one version of the dialogue, I-Pin tells him that she is interested in him, which is why she is stalking him. In response, Hibari replies, "If that's true, I'm flattered." Also, in one possible dialogue version, the fake I-Pin can ask Hibari to go on a walk with Kyoya to gather information about him. Eventually, another character arrives and jokes that Kyoya is popular and seems to be on a date with I-Pin, which is quite unexpected! Tail in Love novel I-pin secretly comes to see Hibari Kyoya, unintentionally leaving chaos in her wake due to her lovestruck Explosion Mode. Even though Hibari does not know who the killer is, he is impressed by her skills and is extremely excited, even trying to force information out of Reborn through threats, showing his indirect respect for I-Pin's skills. source novel (in Russian) Katekyo Hitman Reborn Mobile Game In this game, there's a small story about Hibari and Ipin where Ipin actually trying to collect Hibari's personal data by paper, Ipin also asked Kusakabe about it, it is unknown whether Hibari knows about that but in the end of game's story, he picks up the paper that Ipin writes, then smiles for it. source youtube