Psycho-Pass, Cross Ange: Tenshi to Ryuu no Rondo Recommendations
Both anime story center around a group whose members consist of peoples who are rejected by society but in the end they were forced to protect and serve the public as a punishment for their status.
In Psycho-pass there are called "latent criminal"
In Cross ange there are called "norma"
That type peoples, in fact, not dangerous. But for some conditions, rules, and laws cause them isolated from society.
Another similarity, both anime MC consist of a group created from "rejected peoples" as I already mentioned earlier.
Arzenal Team (Cross Ange) & Unit One of Public Safety Bureau's Criminal Investigation Division (Psycho-pass)