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She has a much bigger part in the manga. She's a real psycho...

Name: Fuma Monou
Anime: X/1999
Proof: Link
Picture:
Banner: I'll make my own

Hm~ I don't know about that... she sounds really horrible! *-*

But the club is called "an anime villain", so shouldn't the charas be from an anime? I don't really know. However, if you want me to remake your banner, I'll ask of you to be a lil patient.

So you want me to remake it or it's ok with that?

Name: Henrietta
Anime: Gunslinger Girl
Proof: Read Gunslinger Girl.
Banner: yes please
Pic: http://img49.imageshack.us/img49/1958/gunslingergirl92go3.jpg

Name: Triela
Anime: Gunslinger Girl
Proof: Read Gunslinger Girl.
Banner: yes please
Pic: http://img152.imageshack.us/img152/8493/gunslingergirl827lr6.jpg

Can you make 1 banner with those two pics?

I guess it won't be a problem! ^^

{ADDED}

Ah, right ^^'
I thought we would be able to claim manga characters as well, but I since I don't want to be a bother I'll go with this banner :) (so my claim is Bara Suishou now)

I guess as I was the reason for all that trouble, I must have to apologise and make you the banner of Kira Kishou. (the apology is a 3rd claim and that is Bara Suisho)

Name: Johan Liebert
Anime: Monster
Proof that he is villain: He's the "monster" that the title refers to. And not only has he been called a monster, but also called the next Adolf Hitler and the devil himself. If that's not proof enough, well...he's an intelligent, cold, brillantly manipulative serial killer.
Picture:
Yeah, I know it's fanart, but the pic was so prettyful! D:
Banner: Yes plz to be making banner? :D

2nd claim X3

Xemnas
Manga: Kingdom Hearts 2
Proof he's a villain: He's an unfeeling, manipulative, and powerful, son of a *****

picture:

Name: Hecate
Anime: Shakugan no Shana
Proof: She is one of the trinity of Bal Masqué, which is the faction that is fighting against flame hazes. Read more here: Bal Masque
Banner: yup, definitely!
Picture:

Name: Kaworu Nagisa
Anime: Neon Genesis Evangelion
Proof: Although he quickly befriended Shinji Ikari, the show's frail and introverted hero, he is actually Here is the climatic battle between NERV, Shinji, and Kaworu----->ep. 24 fight: Shinji v Kaworu. During this battle, Shinji is put through the most difficult mental ordeal in the series. He must decide between two things: Fulfill his duty as an Eva pilot and defeat the angel, or save the only true friend he had and let him become one with Adam.
Banner: Yes, please.
Picture:

Name: Dark Saber
Anime: Fate/stay night
Proof that he/she is villain: Aids Dark Sakura. Tries to kill Shiro.
Banner: I'll make one

Name: Caster
Anime: Fate/stay night
Proof that he/she is villain: Tries to kill Saber, Shiro, Rin. Tries to sacrifice Sakura and Rin.
Banner: I'll make one

Name: Califa
Anime: One Piece
Proof that he/she is villain: She tries to kill the main characters and
Picture: about the only picture on the internet XD
Banner: yes Please

Name: Alexander Anderson
Anime: Hellsing (Ultimate)
Proof that he/she is villain: Also a main character killing kinda person, lot's of guards died by his hands so I'd say he's a bad guy.
Picture:
Banner: Yes please

Name:Balalaika
Anime:Black Lagoon
Proof that he/she is villain: She is the boss of the Russian mafia called Hotel Moscow
Picture:
Banner: yes please

Name: Ophelia
Anime: Claymore
Proof that he/she is villain: She tries to kill the main character. She likes killing.
Picture: http://i234.photobucket.com/albums/ee135/Dragonfly0910/claymore/5973.jpg
Banner: Yes, please.

2nd hire....
Name: Illyasviel von Einzbern (Illya for short)
Anime: Fate/stay Night
Proof: She's the initial adversary for Shirō and Saber. She's also the master of Berserker.
Banner: I'll be making my own....

1st hire
Name: Mihael "Mello" Keehl
Anime: Death Note
Proof: Member of mafia, killer, kidnapper
Banner: I'll Make my own ^^

2nd hire
Name: Kisame Hoshigaki
Anime: Naruto (Shippuuden)
Prooff: Akatsuki member, tried to kill some of the main characters
Banner: I'll make my own